Hubble et. al. report Diffusivities for water in these polymers:
Mylar A (poly (ethylene terephthalate) ): 5.45 x 10-9 cm2/s at 30°C.
Kapton H (polyimide): 3.45 x 10-9 cm2/s at 30°C.
Parylene C (poly(chloro-p-xylylene) 2.60 x 10-9 cm2/s at 30°C.
Crank, in his "Diffusion in Polymers", surveys diffusivity D of water in a wide range of polymers (in his Table V starting on page 274):
|
T |
D x 109 |
ED |
|
|
°C |
cm2/s |
kcal/mole |
|
|
Polyvinyl alcohol |
25 |
0.051 |
14 |
|
Wool |
35 |
0.1 |
|
|
Vinylidene chloride (81) acrylonitrile (19) copolymer |
25 |
0.32 |
20.2 |
|
Rubber hydrochloride |
25 |
0.41 |
14 |
|
Nylon 6 |
25 |
0.97 |
|
|
Regenerated cellulose |
25 |
<1 |
|
|
Polyethyleneterephthalate |
25 |
3.9 |
10.4 |
|
Polyvinylbuteral |
25 |
13 |
10.9 |
|
Polyvinylchloride |
30 |
16 |
10 |
|
Cellulose Acetate |
30 |
17 |
5.6 |
|
Polyvinylchloride (plasticized) |
30 |
17 |
|
|
Polyvinylchloride |
30 |
23 |
42 |
|
Cellulose Acetate (plasticized) |
25 |
30 |
|
|
Polyvinyl acetate |
25 |
43 |
12.5 |
|
Polyvinylchloride(87)-acetate(13) copolymer |
32 |
60 |
7.7 |
|
Polyethylmethacrylate |
25 |
105 |
8.7 |
|
Polymethylacrylate |
25 |
120 |
16 |
|
Polymethylmethacrylate |
50 |
130 |
11.6 |
|
Ethyl cellulose |
24 |
180 |
6.3 |
|
Polyethylene (d=0.922) |
25 |
230 |
14.2 |
|
Polyethylene (d=0.907) |
25 |
240 |
16.4 |
|
Polydimethylsiloxane |
35 |
~70000 |
3 |
Here we see that the diffusivity of water in all three of the film forming polymers Hubble et al. studied, Mylar A, Kapton H and Parylene C, are toward the lower end of the range of values for D in the Crank survey, although they are otherwise unexceptional.